Repository of Research and Investigative Information

Repository of Research and Investigative Information

Ilam University of Medical Sciences

Performance intensification of BzP photo-catalytic degradation through adding exogenous oxidant

Mon Sep 26 13:06:28 2022

(2020) Performance intensification of BzP photo-catalytic degradation through adding exogenous oxidant. Optik. p. 11. ISSN 0030-4026

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Abstract

This study was conducted to investigate the photocatalytic removal of Benzylparaben (BzP) using UVC/ZnO (UZ) process in the presence of H2O2 (UZH) from aqueous solutions. The results indicated that mean size and surface area of nano-ZnO were 30 nm and 150 m(2)/g, respectively. The maximum degradation and mineralization of BzP (15 mg L-1) by UZ process under optimum operational conditions (pH: 9.0, catalyst dose: 1 gL(-1) within 90 min reaction), were over 67.37 and 42 of TOC, respectively. The addition of H2O2 (up to 10 mmol L-1) along with UV/ZnO resulted to 100 and 55 removal of BzP and TOC during 25 min of reaction time, respectively. The kinetic studies indicated r(obs) value for UZH process was about 1101.6, 413.12, 367.22, 27.31 and 18.99 times than that of the ZnO, H2O2, UV, UZ and UV/H2O2 (UH), respectively. The values of energy consumption for UV, UZ, UH and UZH were calculated 1280, 95.2, 66.2 and 3.48 kWh m(-3), respectively. BzP was converted to a biodegradable waste after a 90 min and 25 min irradiation time in the UV/ZnO and UV/ZnO/H2O2 processes, respectively.

Item Type: Article
Creators:
CreatorsEmail
Sheikhmohammadi, A.UNSPECIFIED
Nourmoradi, H.UNSPECIFIED
Manshouri, M.UNSPECIFIED
Asgari, E.UNSPECIFIED
Keywords: Photocatalytic Degradation Mineralization Benzylparaben Biodegradability methylene-blue dye photocatalytic degradation waste-water aqueous-solution organic pollutants ethyl paraben oxidation ozonation kinetics removal Optics
Divisions:
Page Range: p. 11
Journal or Publication Title: Optik
Journal Index: ISI
Volume: 202
Identification Number: https://doi.org/10.1016/j.ijleo.2019.163571
ISSN: 0030-4026
Depositing User: مهندس مهدی شریفی
URI: http://eprints.medilam.ac.ir/id/eprint/2638

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